Tolman’s law in linear irreversible thermodynamics: A kinetic theory approach

Irreversible Thermodynamics and Rate Theory.

Introduction.-The "classical theory of irreversible thermodynamics"1 may be said to have its origin in the formulation of the "reciprocity relations" by Onsager.2 The basis of this theory may be summarized briefly as follows (for a complete discussion see works cited in ref. 1 and 2): in the limit of small excursions from thermodynamic equilibrium, changes in the properties of any system are de...

Coupled heat devices in linear irreversible thermodynamics.

Full analytical models of heat engines and refrigerators in linear irreversible thermodynamics can be defined by means of a chain of coupled heat devices. In this way it is possible to derive results and techniques of finite-time thermodynamics, like endoreversible efficiencies and the usual models of irreversible heat devices, in terms of an endoreversible energy converter plus a heat leak bet...

Irreversible Thermodynamics

There are alternative sets of postulates which yield entirely equivalent results for several important theories. In such cases the choice of a particular set of postulates may be based upon mathematical simplicity, close relationship to experiments or to the nature of the theory, or merely personal taste. While the postulate of conservation of energy is usually presented in similar form for the...

Non-linear Thermoelasticity, Irreversible Thermodynamics and Elastic Instability

1. Introduction. In the linear range a general theory of thermoelasticity based on irreversible thermodynamics was developed and discussed extensively in some earlier work ([3], [4], [9]). It was assumed that the elastic solid is initially in a stress-free equilibrium state at uniform temperature. Completely linearized perturbations in the vicinity of this equilibrium state are then analyzed as...

Basics of Irreversible Thermodynamics